This presentation
seeks to explain the characteristics of Ethanol,
which has been billed as an alternative source
of energy. The importance of petroleum products
in terms of its fluctuating cost and the political
sensitivity in terms of its uninterrupted supply
cannot be overemphasized. This paper will also
answer if Ethanol is cost effective. Besides the
cost factor and the political implications there
is yet another important aspect that is the environmental
friendly nature of Ethanol compared to fossil
fuels like petroleum, coal, and natural gas which
are a major source of pollution. Therefore the
world is looking to sources of energy other than
the fossil fuels. Cold fusion is one such option
being researched. It is in this same context that
Ethanol assumes great importance. This study will
therefore be attempting to enlighten the readers
with a topic of current interest.
Analysis
Let us look at this interesting piece of information:
In 2004, U.S. ethanol facilities will set new
production records and consumers will use more
than 3 billion gallons of ethanol in their automobile”.
(Chemical of the Week -- Ethanol2004)
The above quote is revealing in that Ethanol’s
use has gained acceptance at a level where it
is no longer in the ‘experimental’
or ‘exploratory’ stage. Though nowhere
as common as say motor gasoline it nevertheless
has assumed a promising beginning in the commercial
sense.
Someone who is uninitiated would be right in
posing the legitimate question ‘what is
Ethanol’? Ethanol is an alcohol, clear and
colorless. In dilute form it has a sweet flavor
but as a concentrated solution it has a burning
taste. In ancient times it was made by fermentation
of sugar. Even now when used as a beverage ethanol
is made by this method. What is more, this process
also makes half of industrial ethanol. Simple
sugars are the raw material.
Ethanol is easy to prepare. No elaborate production
equipment or technological know-how is required.
It can be made in the backyard. Many people are
doing just that to run their vehicles on clean
burning fuel and reducing their dependence on
the leaded gasoline. In the United States such
backyard producers require a “small fuel
producer” permit from the US Bureau of Alcohol,
Tobacco and Firearms. This can be easily acquired.
Denaturing is not required for ethanol consumed
on premises.
A few chemical details about Ethanol. Its chemical
formula is CH3CH2OH and its molecule contains
a hydroxyl group, –OH, bonded to a carbon
atom. Ethanol melts at –114.1°C, boils
at 78.5°C, and has a density of 0.789 g/ml
at 20°C. Because of its low freezing point
it is used as a fluid in thermometers for recording
temperatures below –40°C, the freezing
point of mercury, and as antifreeze in car radiators.
The American Coalition for Ethanol maintains that
Ethanol is a high-performance motor fuel that
reduces the poisonous exhaust emissions and is
therefore environment friendly. In the United
States over 15 billion gallons of ethanol-blended
petrol is used annually. This volume constitutes
12 percent of total fuel sales in the U.S. And
this figure is increasing with every passing year.
Most of the ethanol used is 10 percent blend but
85% to 95% blends are also being tested. Brazil,
by comparison, uses 4 billion gallons a year.
All fuels in Brazil have a 24 % ethanol content
and most of it is 100% ethanol for car engines
designed for the same. Leading automobile manufacturers
recommend ethanol and include it in their warranty
coverage. An interesting statistic is that over
two trillion miles have been driven in the U.S.
on ethanol-blended fuels since 1980. (Ethanol:
Journey to Forever 2004)
Ethanol has a higher octane rating (increases
the octane rating by three percent) compared to
ordinary motor gasoline. It replaces lead as the
octane enhancer in gasoline. Ethanol adds oxygen
to the fuel and therefore it burns more completely
which reduces emissions of carbon monoxide. Ethanol
and ETBE oxygenator, made from ethanol, are much
safer than the toxic and polluting MTBE (Methyl
Tertiary Butyl Ether) fossil-fuel-derived oxygenator
used by oil companies. These are big plus points
for ethanol (Ethanol: Journey to Forever 2004)
In Canada ethanol is made from corn because Canada
has surplus corn production. Now we know that
energy is required in (i) growing corn and (ii)
in making ethanol out of grain corn. So the energy
gained from ethanol must be greater than the combined
input in (i) and (ii) above. The following table
has figures from actual research conducted:
Summary of Energy Inputs and Outputs
According to the 1995 study produced by the Institute
for Local Self-Reliance, using state-of-the-art
farming and ethanol production techniques would
result in the following energy balance:
INPUTS BTU's/Litre of Ethanol
INPUTS - FEEDSTOCK
Fertilizer 1,022
Pesticides 107
Fuel 349
Irrigation 1,597
Other 825
Total 3,901
INPUTS - PROCESSING
Process Steam 6,917
Electricity 1,360
Bulk Transport 211
Other 277
Total 8,766
TOTAL ENERGY INPUT 12,667
OUTPUTS
Energy in Ethanol 22,217
Co-product Credits 9,579
TOTAL ENERGY OUTPUT 31,796
NET ENERGY GAIN 19,130 = 151%
(Canadian Renewable Fuels Association - Energy
Balance of Ethanol 2004)
Ceramics Fuel Cells Limited has claimed that its
particular fuel cell design will be able to generate
clean electricity utilizing ethanol, a totally
renewable environment friendly fuel.
(Ethanol shows promise as renewable source of
hydrogen for fuel cells 2004)
A research conducted at the Institute of Local
Self-Reliance in the US determined that using
latest farming techniques, "the amount of
energy contained in a gallon of ethanol is more
than twice the energy used to grow the corn and
convert it to ethanol". (Ethanol: Journey
to Forever 2004)
Ethanol can be used as a transport fuel in spark
ignition engines. It has high-octane levels and
can be either blended into petrol and used in
unmodified vehicles, or run as 100 percent ethanol
in a converted engine. When produced from agricultural
biomass, i.e. bio-ethanol,
it becomes a renewable fuel. The issues here
are cost and source of the ethanol, distribution
of the fuel, performance of vehicles, and safety
and environmental issues. In New Zealand experts
determined that blends of up to 10 percent ethanol
in petrol (E10) will not reduce performance of
cars. Studies in New Zealand indicated that the
country could produce enough maize and sugar beet
to replace all petrol in New Zealand. Blending
can be at bulk storage terminals or during truck
loading which process is known as "Splash
blending". Using ethanol blend does not enhance
emission levels. As bio-ethanol is renewable,
CO2 emitted during combustion is taken up in the
biomass feedstock. But since ethanol itself requires
energy to be produced it is not entirely carbon
neutral. CO2 emitted during manufacture is between
30 to 90 percent of CO2 emitted during combustion
of ethanol depending on the efficiency of the
technology employed. An E10 blend is estimated
to give a net CO2 saving of between 1.5 percent
and 5.5 percent. (Bio-ethanol as a Transport Fuel?
2004)
In 2002 the Bush administration urged U.S. Senate
and House lawmakers negotiating an energy bill
to pass legislation that would triple the amount
of ethanol-blended gasoline and biodiesel used
each year in American cars, trucks and SUV’s.
In October 2004 President Bush signed tax measure
to benefit the ethanol industry. This shows the
President’s commitment to renewable energy.
(President Bush signs critical ethanol tax measures
into law’ 2004)
Ethanol fuel production provides local jobs and
a market for local materials, and helping to keep
money and investment within the community. Because
of these advantages all the farming states in
North America back ethanol fuel. Besides job creation
and increased farm income, use of ethanol improves
air quality, and provides greater energy independence
by reducing imports of foreign oil. A Minnesota
farm converts 11,751 bushes a day to produce 33,990
gallons of ethanol and 95 tons of high-protein
animal feed. It is estimated that an acre of sugar
cane cultivation can yield enough ethanol to drive
a four by four vehicle for 15,000 miles. An acre
of corn will give less mileage say about 5,000
miles.
The advantages of ethanol can be summarized as
follows:
• It does not require high technology to
manufacture
• It is a renewable fuel made from plants
o Because it is not a fossil-fuel its manufacture
and burning it does not increase the greenhouse
effect
• It replaces harmful fuel additives and
is also cost effective
• Ethanol blends can be used in all petrol
engines without modifications
• It significantly cuts down poisonous exhaust
emissions
• The high oxygen content of ethanol cuts
down carbon monoxide levels more than any other
oxygenate: by 25-30%, according to the US EPA
• Ethanol blends significantly bring down
reduce emissions of hydrocarbons, a major contributor
to the depletion of the ozone layer
• High-level ethanol blends reduce nitrogen
oxide emissions by up to 20%
• Ethanol can reduce net carbon dioxide
emissions by up to 100% on a full life-cycle basis
• High-level ethanol blends can reduce emissions
of Volatile Organic Compounds (VOCs) by 30% or
more (VOCs are major sources of ground-level ozone
formation)
• Ethanol reduces emissions of such harmful
substances as Sulphur dioxide,Particulate
Matter (PM), benzene and butadiene
• Ethanol use reduces the U.S. trade deficit
by $2 billion annually
• Ethanol reduces the need to import 128,000
barrels a day of oil
• Ethanol helps to diversify our energy
infrastructure with local production of renewable
fuel.
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